Dissolved organic matter variations in coastal plain wetland watersheds: The integrated role of hydrological connectivity,land use,and seasonality          下载免费PDF全文

Jacob D. Hosen  Alec W. Armstrong  Margaret A. Palmer 《水文研究》2018,32(11):1664-1681

Dissolved organic matter (DOM) is integral to fluvial biogeochemical functions, and wetlands are broadly recognized as substantial sources of aromatic DOM to fluvial networks. Yet how land use change alters biogeochemical connectivity of upland wetlands to streams remains unclear. We studied depressional geographically isolated wetlands on the Delmarva Peninsula (USA) that are seasonally connected to downstream perennial waters via temporary channels. Composition and quantity of DOM from 4 forested, 4 agricultural, and 4 restored wetlands were assessed. Twenty perennial streams with watersheds containing wetlands were also sampled for DOM during times when surface connections were present versus absent. Perennial watersheds had varying amounts of forested wetland (0.4–82%) and agricultural (1–89%) cover. DOM was analysed with ultraviolet–visible spectroscopy, fluorescence spectroscopy, dissolved organic carbon (DOC) concentration, and bioassays. Forested wetlands exported more DOM that was more aromatic‐rich compared with agricultural and restored wetlands. DOM from the latter two could not be distinguished suggesting limited recovery of restored wetlands; DOM from both was more protein‐like than forested wetland DOM. Perennial streams with the highest wetland watershed cover had the highest DOC levels during all seasons; however, in fall and winter when temporary streams connect forested wetlands to perennial channels, perennial DOC concentrations peaked, and composition was linked to forested wetlands. In summer, when temporary stream connections were dry, perennial DOC concentrations were the lowest and protein‐like DOM levels the highest. Overall, DOC levels in perennial streams were linked to total wetland land cover, but the timing of peak fluxes of DOM was driven by wetland connectivity to perennial streams. Bioassays showed that DOM linked to wetlands was less available for microbial use than protein‐like DOM linked to agricultural land use. Together, this evidence indicates that geographically isolated wetlands have a significant impact on downstream water quality and ecosystem function mediated by temporary stream surface connections.  相似文献   

Towards Quantifying the Likelihood of Water Resource Impacts from Unconventional Gas Development     

Margaret Shanafield  Peter G. Cook  Craig T. Simmons 《Ground water》2019,57(4):547-561

Gas production from unconventional reservoirs has led to widespread environmental concerns. Despite several excellent reviews of various potential impacts to water resources from unconventional gas production, no study has systematically and quantitatively assessed the potential for these impacts to occur. We use empirical evidence and numerical and analytical models to quantify the likelihood of surface water and groundwater contamination, and shallow aquifer depletion from unconventional gas developments. These likelihoods are not intended to be exact. They provide a starting point for comparing the probabilities of adverse impacts between types of water resources and pathways. This analysis provides much needed insight into what are “probable” rather than simply “possible” impacts. The results suggest that the most likely water resource impacts are surface water and groundwater contamination from spills at the well pad, which can be as high as 1 in 10 and 1 in 100 for each gas well, respectively. For wells that are hydraulically fractured, the likelihood of contamination due to inter-aquifer leakage is 1 in 10⁶ or lower (dependent on the separation distance between the production formation and the aquifer). For gas-bearing formations that were initially over-pressurized, the potential for contamination from inter-aquifer leakage after production ceases could be as high as 1 in 400 where the separation between gas formation and shallow aquifer is 500 m, but will be much lower for greater separation distances (more characteristic of shale gas).  相似文献   

First record of the Australian ascidian Eudistoma elongatum in northern New Zealand     

Peter J. Smith  Mike Page  Sean J. Handley  S. Margaret McVeagh  Merrick Ekins 《新西兰海洋与淡水研究杂志》2013,47(4):347-355

A colonial ascidian was first reported by marine farmers in Houhora Harbour, Northland, New Zealand in early 2005 and subsequently found on oyster racks in Parengarenga Harbour and the Bay of Islands. The Northland ascidian was identified with a combination of morphological characters and DNA cytochrome c oxidase I (COI) sequence data, as Eudistoma elongatum, a species native to Australia, where it is found from northern New South Wales to Northern Queensland, and distinguished from Eudistoma circumvallatum, the only reported species in this genus from New Zealand. Ascidian larvae are weak dispersers and long distance dispersal of E. elongatum is likely to be enhanced by vectors such as oyster barges and/or movement of cultured oysters. In its native range, E. elongatum is restricted to areas with a minimum winter sea temperature of 16°C. Assuming similar biological limitations apply in New Zealand, the spread of E. elongatum might be restricted to northern New Zealand (north of latitude 37°S).  相似文献   

Run‐off processes from mountains to foothills: The role of soil stratigraphy and structure in influencing run‐off characteristics across high to low relief landscapes          下载免费PDF全文

Margaret A. Zimmer  John P. Gannon 《水文研究》2018,32(11):1546-1560

The critical zone features that control run‐off generation, specifically at the regional watershed scale, are not well understood. Here, we addressed this knowledge gap by quantitatively and conceptually linking regional watershed‐scale run‐off regimes with critical zone structure and climate gradients across two physiographic provinces in the Southeastern United States. We characterized long‐term (~20 years) discharge and precipitation regimes for 73 watersheds with United States Geological Survey in‐stream gaging stations across the Appalachian Mountain and Piedmont physiographic provinces of North Carolina. Watersheds included in this analysis had <10% developed land and ranged in size from 14.1–4,390 km². Thirty‐four watersheds were located in the Piedmont physiographic province, which is typically classified as a low relief landscape with deep, highly weathered soils and regolith. Thirty‐nine watersheds were located in the Appalachian Mountain physiographic province, which is typically classified as a steeper landscape with highly weathered, but shallower soils and regolith. From the United States Geological Survey daily mean run‐off time series, we calculated annual and seasonal baseflow indices (BFI), minimum, mean, and maximum daily run‐off, and Pearson's correlation coefficients between precipitation and baseflow. Our results showed that Appalachian Mountain watersheds systematically had higher minimum daily flows and BFI values. Piedmont watersheds displayed much larger deviations from mean annual BFI in response to year‐to‐year variability in precipitation. A series of linear regression models between 21 landscape metrics and annual BFIs showed non‐linear and complex terrestrial–hydrological relationships across the two provinces. From these results, we discuss how distinct features of critical zone architecture, with specific focus on soil depth and stratigraphy, may be dominating the regulation of hydrological processes and run‐off regimes across these provinces.  相似文献   

    

Margaret Armstrong 《Mathematical Geology》1985,17(8):855-859

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Frequency dependence of Q in the mantle underlying the shield areas of Eurasia, Part II: analyses of long period data     

Alison C. Lees  Zoltan A. Der  Vernon F. Cormier  Margaret E. Marshall  James A. Burnetti 《Geophysical Journal International》1986,87(3):1085-1101

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Unleakable carbon†     

Margaret F. Hendrick  Shanna Cleveland  Nathan G. Phillips 《Climate Policy》2013,13(8):1057-1064

Unleakable carbon, or the uncombusted methane and carbon dioxide associated with fossil fuel systems, constitutes a potentially large and heretofore unrecognized factor in determining use of Earth’s remaining fossil fuel reserves. Advances in extraction technology have encouraged a shift to natural gas, but the advantage of fuel switching depends strongly on mitigating current levels of unleakable carbon, which can be substantial enough to offset any climate benefit relative to oil or coal. To illustrate the potential warming effect of methane emissions associated with utilizable portions of our remaining natural gas reserves, we use recent data published in peer-reviewed journals to roughly estimate the impact of these emissions. We demonstrate that unless unleakable carbon is curtailed, up to 59–81% of our global natural gas reserves must remain underground if we hope to limit warming to 2°C from 2010 to 2050. Successful climate change mitigation depends on improved quantification of current levels of unleakable carbon and a determination of acceptable levels of these emissions within the context of international climate change agreements.

Policy relevance

It is imperative that companies, investors, and world leaders considering capital expenditures and policies towards continued investment in natural gas fuels do so with a complete understanding of how dependent the ultimate climate benefits are upon increased regulation of unleakable carbon, the uncombusted carbon-based gases associated with fossil fuel systems, otherwise referred to as ‘fugitive’, ‘leaked’, ‘vented’, ‘flared’, or ‘unintended’ emissions. Continued focus on combustion emissions alone, or unburnable carbon, undermines the importance of assessing the full climate impacts of fossil fuels, leading many stakeholders to support near-term mitigation strategies that rely on fuel switching from coal and oil to cleaner burning natural gas. The current lack of transparent accounting of unleakable carbon represents a significant gap in the understanding of what portions of the Earth’s remaining global fossil fuel reserves can be utilized while still limiting global warming to 2°C. Successful climate change mitigation requires that stakeholders confront the issue of both unburnable and unleakable carbon when considering continued investment in and potential expansion of natural gas systems as part of a climate change solution.  相似文献   

Standards for faecal coliform bacterial pollution     

Margaret Loutit  I. L. Vidal  A. A. Collins 《新西兰海洋与淡水研究杂志》2013,47(1-2):214-219

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The Global boundary Stratotype Section and Point （GSSP） of the Drumian Stage （Cambrian） in the Drum Mountains, Utah, USA     

Loren E. Babcock Richard A. Robison Margaret N. Rees Shanchi Peng Matthew R. Saltzman 《《幕》》2007,30(2):85-95

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